Kisame Hoshigaki and Zabuza Momochi (Seven Swordsmen of the Mist) - (DLC).Naruto Storm 4 DLC Pack 3: Playable Characters Rock Lee, Neji Hyūga, and Tenten - (DLC).Sasuke Uchiha and Itachi Uchiha - (DLC).Naruto Storm 4 DLC Pack 2: Another Scenario Pack #2 Kiba Inuzuka, Shino Aburame, and Hinata Hyūga - (DLC).Shikamaru Nara and Asuma Sarutobi - (DLC).Hokage (Hashirama Senju, Tobirama Senju, Hiruzen Sarutobi, Minato Namikaze, Tsunade, and Kakashi Hatake) - (DLC).Naruto Uzumaki (Seventh Hokage, Costume) and Boruto Uzumaki (Super Uzumaki Rasengan) - (DLC).Naruto Storm 4 DLC Pack 1: Another Scenario Pack #1
Just like any other game they just have to add some some DLC :( You can check the release date and other content the DLC will contain in the link below. You have to purchase the DLC if you want to use these Jutsu. Killer B and A (Liger Two Platoons Bomb).Jinchūriki (Naruto Uzumaki, Gaara, Killer B, Yugito Nii, Yagura, Rōshi, Han, Utakata, Fū).Gaara, Temari and Kankurō (Scorching Heat Sand Binding Coffin).Shikamaru Nara, Ino Yamanaka and Chōji Akimichi (Human Bullet Yo-Yo).Jiraiya, Orochimaru and Tsunade (Fire Leaping Windhole).